期刊
ACS Applied Nano Materials
标题
Tunable Photocatalytic Properties of Au-Decorated BiFeO3 Nanostructures for Dye Photodegradation
作者
Jhen-Yang Wu, Chun-Yi Chen, Junan Wang, Xinyu Jin, Wending Hou, Hsuan-Hung Kuo, Wan-Ting Chiu, Tomoyuki Kurioka, Masato Sone, Satoshi Okamoto, Yung-Jung Hsu, and Tso-Fu Mark Chang
摘要
This study presents the synthesis and characterization of Au nanoparticle-decorated BiFeO3 (Au-BiFeO3) nanocrystals fabricated by a hydrothermal technique. The key focus is the augmented photocatalytic properties of these nanocrystals for the effective photodegradation of methylene blue (MB), a common industrial dye. The magnetic properties of the Au-BiFeO3 merely differ from those of the BiFeO3. The decoration of Au nanoparticles onto the BiFeO3 introduces heterojunction structures that lead to effective charge-carrier separation under illumination. Time-resolved photoluminescence spectroscopy confirms the enhanced charge separation and reduced recombination rate in Au-BiFeO3 nanocrystals. Through meticulous optimization, the photocatalytic performance of these nanocomposites was evaluated under various Au loadings, revealing that 1.0 wt % Au-BiFeO3 exhibits the most superior activity, achieving an impressive 98% degradation efficiency of MB under a 500 W xenon lamp within 120 min. The study also demonstrates the structural integrity and stability of the photocatalyst, with it retaining about 80% of its original activity after four cycles of the 120 min photodegradation process. These findings suggest that the Au-BiFeO3 nanocrystals are promising, efficient, and sustainable photocatalysts for environmental purification and offer insights into designing advanced materials for solar energy utilization.
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