期刊

Angewandte Chemie, International Edition

标题

Merging Photoredox and Organometallic Catalysts in a Metal–Organic Framework Significantly Boosts Photocatalytic Activities

作者

Prof. Yuan‐Yuan Zhu, Guangxu Lan, Yingjie Fan, Samuel S. Veroneau, Yang Song, Daniel Micheroni, Prof. Wenbin Lin

摘要

Incorporation of two metal catalysts in a metal–organic framework (MOF) can lead to enhanced turnover numbers. In their Communication on page 14090, W. Lin et al. exemplify this strategy by combining an IrIII photoredox catalyst and a NiII cross‐coupling catalyst within a stable Zr12 MOF for C−S bond formation between various aryl iodides and thiols. The proximity of the IrIII and NiII catalytic components greatly facilitates electron and thiol radical transfers.

原文链接

https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.201811111