期刊

Chemistry - A European Journal

标题

Selective Transformation of Well‐Defined Alkenyllithiums to Alkenylmagnesiums via Transmetalation

作者

Miaomiao Zhu, Liang Liu, Yongliang Zhang, Hai‐Tao Yu, Wen‐Xiong Zhang, Zhenfeng Xi

摘要

Selective transformation of alkenyllithiums to alkenylmagnesiums via simple transmetalation has been achieved. The synthesis, structure, and mutual transformation of three different organomagnesiums by adding Grignard reagent and/or MgCl2 to dilithio reagents are described. These magical transformations triggered by Grignard reagent and/or MgCl2 are similar to the traditional Face‐changing art originating from the Sichuan province of China.

原文链接

https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.201705831