期刊

Dalton Transactions

标题

FLP reactivity of [Ph3C]+ and (o-tolyl)3P and the capture of a Staudinger reaction intermediate

作者

Jiliang Zhou, Levy L. Cao, Liu (Leo) Liu and Douglas W. Stephan

摘要

The frustrated Lewis pair (FLP) derived from the trityl cation and (o-tolyl)3P effects the activation of 1,4-cyclohexadiene and 1-bromo-4-ethynylbenzene and heterolytically cleaves the S–S bond of diphenyl disulfide. The FLP also captures pentafluorophenyl azide as the Staudinger reaction intermediate, a species that reacts with Ph3SiH to give the silyl analog.

原文链接

http://pubs.rsc.org/en/content/articlelanding/2017/dt/c7dt01726j#!divAbstract