期刊:
Angewandte Chemie
标题:
Solvent-Assisted Metal Metathesis: A Highly Efficient and Versatile Route towards Synthetically Demanding Chromium Metal–Organic Frameworks
作者:
Dr. Jun-Hao Wang, Dr. Ying Zhang, Mian Li, Shu Yan, Prof. Dan Li, Prof. Xian-Ming Zhang
摘要:
Owing to their extraordinary robustness and high porosity, chromium(III)-based metal–organic frameworks (Cr-MOFs) have great potential, but they are currently difficult to synthesize. In their Communication on page 6478 ff., J. H. Wang, X. M. Zhang et al. describe the preparation of a variety of Cr-MOFs from the corresponding Fe-MOFs under mild conditions by solvent-assisted metal metathesis. This efficient and versatile strategy constitutes a promising route for the synthesis of stable MOFs.
原文链接:
http://onlinelibrary.wiley.com/doi/10.1002/anie.201703997/abstract