期刊
Angewandte Chemie
标题
Facile Synthesis of N-Carboranyl Amines through an ortho-Carboryne Intermediate (Angew. Chem. Int. Ed. 5/2016) (page 1926)
作者
Ruofei Cheng, Jie Zhang, Jiji Zhang, Prof. Dr. Zaozao Qiu and Prof. Dr. Zuowei Xie
摘要
An efficient o-carboryne precursor 1-Li-2-OTf-o-C2B10H10 has been developed, which undergoes addition with lithium amides to give a series of N-carboranyl amines in moderate to high yields with a broad substrate scope. This represents the first general method for the synthesis of 1-R1R2N-o-carboranes.
原文链接
http://onlinelibrary.wiley.com/doi/10.1002/anie.201507952/full