期刊
Nano Letters
标题
Lattice -Mismatch-Induced Ultrastable 1T-Phase MoS2–Pd/Au for Plasmon-Enhanced Hydrogen Evolution
作者
Bo Shang,Xiaoqiang Cui,Lin Jiao,Kun Qi,Yingwei Wang,Jinchang Fan,Yuanyuan Yue,Haiyu Wang,Qiaoliang Bao,Xiaofeng Fan,Shuting Wei,Wei Song,Zhiliang Cheng,Shaojun Guo,Weitao Zheng
摘要
Metallic 1T-phase transition metal dichalcogenides (TMDs) are of considerable interest in enhancing catalytic applications due to their abundant active sites and good conductivity. However, the unstable nature of 1T-phase TMDs greatly impedes their practical applications. Herein, we developed a new approach for the synthesis of highly stable 1T-phase Au/Pd-MoS2 nanosheets (NSs) through a metal assembly induced ultrastable phase transition for achieving a very high electrocatalytic activity in the hydrogen evolution reaction. The phase transition was evoked by a novel mechanism of lattice-mismatch-induced strain based on density functional theory (DFT) calculations. Raman spectroscopy and transmission electron microscopy (TEM) were used to confirm the phase transition on experimental grounds. A novel heterostructured 1T MoS2–Au/Pd catalyst was designed and synthesized using this mechanism, and the catalyst exhibited a 0 mV onset potential in the hydrogen evolution reaction under light illumination. Therefore, this method can potentially be used to fabricate 1T-phase TMDs with remarkably enhanced activities for different applications.
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