期刊
Chemical Communications

标题
Synthesis, structure and dehydrogenation of zirconium borohydride octaammoniate

作者

Jianmei Huang, Yingbin Tan, Jiahao Su, Qinfen Gu, Radovan Černý, Liuzhang Ouyang, Dalin Sun, Xuebin Yu and Min Zhu

摘要

A new metal borohydride ammoniate (MBA), Zr(BH4)4·8NH3, was synthesized via ammoniation of the Zr(BH4)4 crystal. Zr(BH4)4·8NH3 has a distinctive structure and the highest coordination number of NH3 groups among all the known MBAs. This compound could quickly dehydrogenate at 130 °C, enabling it a potential hydrogen storage material.

原文链接
http://pubs.rsc.org/en/content/articlelanding/2015/cc/c4cc09317h