期刊

Chemical Communications

标题

Rylene annulated phthalocyanine: a fully conjugated block for the construction of a supramolecular two-dimensional framework

作者

Jiajing Feng,  Lulu Fu, Tengda Huang, Hua Geng, Wei Jiang and  Zhaohui Wang

摘要

A rylene annulated phthalocyanine (ZnPcPDI4) was designed and synthesized. Single-crystal X-ray diffraction analyses unambiguously confirmed the giant molecule quasi-planar “four leaf clover” skeleton with a 27 Å diameter and a two-dimensional cage-like supramolecular structure. The fully conjugated characteristics endowed it with significant Q-band red-shifts to the near-infrared region of 785 nm, and a largely degenerated LUMO level.

原文链接

https://pubs.rsc.org/en/content/articlelanding/2018/cc/c8cc01216d